This is a strange one. Some thumbnail URLs, like the one below, return a Content-Type header of "application/x-www-form-urlencoded", even though it returns PNG content.
https://upload.wikimedia.org/wikipedia/commons/thumb/9/9a/Cholesterol.svg/200px-Cholesterol.svg.png
$ curl -I https://upload.wikimedia.org/wikipedia/commons/thumb/9/9a/Cholesterol.svg/200px-Cholesterol.svg.png HTTP/1.1 200 OK Server: nginx/1.9.4 Date: Fri, 15 Jan 2016 23:26:31 GMT Content-Type: application/x-www-form-urlencoded