As a user reports at fr.wp, it is not natural to see experienced users being visible when you filter your mentees: you expect to only see beginners, or recently created accounts.
To narrow down the result, by excluding some mentees from the list, we will use the same filtering as we have in Recent Changes: registered editors with more than 500 edits and 30 days of activity.
Regarding scaling, I have no idea if mentors would like to keep an eye on their mentees when they pass the "experienced users" threshold.