We currently have no way to track Web2Cit usage.
It has been suggested that logging Web2Cit server requests from Wikipedia may be used as an indirect measure (T302696) of Web2Cit usage. However, we cannot be sure if citations were actually inserted in the end.
We may thus consider further tweaking the Citoid extension to add something (maybe a comment?) to the citation template if it was inserted using Web2Cit-generated data.
In addition, we may consider adding a hidden page category in these cases noting that some citations have been added using Web2Cit.
Although these additions would be useful to understand Web2Cit usage, the Wikipedia community may reasonably not like them, as it would add some clutter to Wikipedia articles.