Enable "MathML (experimental; no images)" in Special:Preferences → Apperance → Math. Then preview a page with the contents <math>a\not=b</math>.
This renders as a=b but it should render as a≠b. This is the MathML generated:
<mstyle displaystyle="true" scriptlevel="0"> <mi>a</mi> <mo stretchy="false">=</mo> <mi>b</mi> </mstyle>
Note it uses = instead of ≠.
For comparison, https://temml.org/ generates
<mrow> <mi>a</mi> <mo>≠</mo> <mi>b</mi> </mrow>