As requeted here, when a new audio-file is exported to Commons, it would be great if this new file had a line with a DEFAULTSORT with the same content as the already existant parameter "transcription".
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In fact, the Template:Lingua Libre record (which is used by all the files uploaded using Lingua Libre) already add the transcription as a sortkey to the Category:Lingua Libre pronunciation-XXX.
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I've just added the defaultsort to the template for manual categorization to also benefit from the sortkey.