This is a side-effect of T103364, but it's always been a bug technically speaking: if you enter a URL into the 'manual' field in the citation tool, Visual Editor gives it to Parsoid as plain text, which means that Parsoid obediently adds <nowiki> tags to ensure that it doesn't accidentally get autolinked.
There's are other issues with autolinking, but handling this one case correctly will help resolve https://en.wikipedia.org/wiki/Wikipedia:VisualEditor/Feedback#External_links_in_references_put_in_nowiki_tags